• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a method and apparatus for processing polymeric materials. Polymeric material processing methods include squeezing the material upon cooling and subsequent action by shear modulated shear stresses with frequencies between 0.3 and 1000 Hz and modulation depths between 0.05 and 1, the maximum shear stress values being between 1 and 50 N. / Mm2 in the range. The compression is achieved at a pressure of 0.7 to 100 MPa, and the action of the amplitude modulated shear stress is performed under predetermined pressure and cooling conditions. The device of the invention comprises a casing 1, a compression screw 5, and a rotor 8, between the compression screw 5 and the rotor 8 and / or the inner surface of the casing 1. Shear stress modulators 7 and 15 are provided respectively at. The shear stress modulator 7 disposed between the compression screw 5 and the rotor 8 is rotatably mounted and is in the form of an oval cylinder, or in the form of a right-sided polyhedral prism, or longitudinal and / or radially on its side. It is designed in the form of a rotating body in which photo recesses are arranged. The shear stress modulator 15 arranged on the inner surface of the casing 1 is designed in the form of a ring-shaped ridge with longitudinal and / or inclined recesses arranged on its surface. According to another embodiment of the present invention, the apparatus of the present invention is provided with a shear stress modulator consisting of two members installed inside the abrasive zone 6, wherein the first member 16 of the shear stress modulator is a compression screw ( It is arranged between 5) and the rotor 8, and the second member 17 of the shear stress modulator is arranged on the inner surface of the casing 1.
    公开号:KR20030041976A
    申请号:KR10-2003-7002689
    申请日:2001-08-22
    公开日:2003-05-27
    发明作者:바딤 젠나디에비치 니콜스키；블라디미르니콜라에비치 발리베르딘
    申请人:바딤 젠나디에비치 니콜스키；
    IPC主号:
    专利说明:

    METHOD FOR PROCESSING POLYMERIC MATERIAL AND DEVICE FOR CARRYING OUT SAID METHOD}
    [2] Methods of treating industrial rubber articles are known in the art, in which mechanical forces are applied to industrial rubber articles reinforced with metal to break down the material to separate the metal reinforcement from the rubber. The action of this mechanical force is carried out in gaseous media containing 0.01 to 10 percent ozone, and the strain value of the industrial rubber article is maintained at at least 1% level as stresses deform the rubber (September 1992). Russian Federation Patent No. N 2060882 of International Classification Code B29B 17/02 dated 17).
    [3] However, because the processing of the rubber article proceeds in an ozone containing medium, the rubber debris produced in this manner has an oxide surface. For this reason, the utility of the products produced is somewhat limited. In particular, rubber articles made from these rubber shavings tend to exhibit a rapid aging phenomenon, so that under certain operating conditions during storage, their key parameters are three to ten times faster than those produced with the first non-oxidized rubber. do.
    [4] Apparatuses for the treatment of industrial rubber articles reinforced with metal cords are known, which comprise a working chamber having a grinding means for destroying industrial rubber products and a supply means for gaseous media therein. It is included. An ozone-containing gas supply source is used as the supply means for the gaseous medium (Russian Federation Patent No. 2060882 to International Classification Symbol B29B 17/02, dated 17 September 1992).
    [5] However, this known device is rather low in actual output and, during operation of the device, it is necessary to apply a special purpose means to protect the operator from the possibility of leakage of ozone containing gas with a significant level of oxidation into the surrounding environment. It is characterized by its complicated operation.
    [6] The prior art closest to the method according to the invention is a method of polishing a polymer material by the simultaneous action of compression and subsequent shear stress and pressure, among which vulcanized rubber, rubber scrap, rubber-fabric material or synthetic rubber It is polished by this method. The compression process is carried out at a pressure of 0.2 to 0.7 MPa, the subsequent shear stress of which is equivalent to 0.03 to 5.0 N / mm 2 at a pressure of 0.2 to 50.0 MPa on the compressive material. This action of compression, shear stress and pressure is carried out during successive repeats of heating to 200 to 100 ° C. and cooling to 100 to 30 ° C. in a single screw or double screw extruder (9 1990 Invention USSR N 1434663 of International Classification Codes B29B 13/10, B29B 17/00 and B02C 19/22 dated May 15).
    [7] However, unfairly high energy consumption is required when processing industrial rubber articles and rubber scrap having synthetic cords using known methods. This is because during material processing in the extruder, maximum shear stresses occur inside the microregions located near the engagement (contact) points of the screw. In addition, the entry of a piece of tire with metal cord or steel wire into the micro area near the engagement point of the screw causes damage and breakage of the screw, and therefore the tire cannot be handled with the metal cord in this way. The number of materials that can be polished is limited. As a result, all attempts so far to treat scrap tires reinforced with metal cords using an extruder have not succeeded in separating the cord and rubber and crushing the rubber. In addition, the continuous repeated heating and cooling of the material lowers the productivity of the process and increases the energy consumption. (According to the data, the energy consumption rate during the polishing of rubber scrap and rubber fabric articles with the above method is 0.5 to 0.7 KW.h or more per kg. For example, according to example 7 of the invention USSR N 1434663). When the rubber is heated and cooled twice, the energy consumption during polishing of the isoprene rubber with fabric cord is equal to 0.6 KW.h / kg, especially 1 to 1.5 KW.h / kg for the treatment of aircraft scrap tires. Even at high energy consumption rates of up to 50%, the rubber cannot be destroyed or the rubber can be completely separated from the cord, so in this case up to 50% of the rubber remains bonded to the cord and separated from the cord through subsequent separation treatment. Can not be). Moreover, because a significantly high shear stress value is required for polishing, it is not possible to produce fine powder from the polymer material when treating a rather high strength polymer material using known methods.
    [8] According to the technical subject matter of the present invention, the prior art closest to the apparatus of the present invention includes a cylindrical casing having a charging opening and a discharging opening, the compression of the casing being inside the casing. There is a device for producing powder from polymeric material, with a compacting screw disposed in the zone and a grinding rotor in the abrasive zone. The surface of the compression screw is formed with a helical groove, the depth of the groove gradually decreases toward the exit. On the other hand, the polishing rotor is mounted coaxially with the casing, and is disposed in line with the compression screw so as to be rotatable in an annular gap with respect to the inner surface of the casing. A ring-shaped hole is cut at an end adjacent to the polishing rotor of the compression screw surface and / or at an end adjacent to the compression screw of the polishing rotor surface. Such a device is provided with a cooling means for cooling the polishing rotor and / or casing in the grinding zone (Russian Federal Patent No. 2057013 of International Classification Code B29B 17/00, dated March 27, 1996).
    [9] Known devices ensure the processing of a wide range of various polymeric materials, especially industrial rubber articles with metal cords, but too high energy consumption (per kg of rubber reinforced with metal cord) 1 kW.h or more) is required. In addition, only coarse rubber powder with a high energy consumption rate and a high content of debris composed of large particles of 2 to 5 mm in size and a small specific surface area is produced. Such powders are limited in their reuse. In addition, for known devices, the separation range of rubber from metal cords appears to be insufficient, about 90-92 percent, and in some cases only 80 percent. This is because, if the energy consumption is less than 0.5 to 1.0 KW.h per kg, the known apparatus cannot realize a high shear stress suitable for most materials. For this reason, as well as composites reinforced with high content of metal wires or synthetic cords, as well as shells of some grains such as buckwheat seeds, polymers such as lamination paper with a low content of low density polyethylene, and other materials using known devices It can't be processed.
    [10] In addition, cooling means positioned only within the grinding zones of the known apparatus may not provide efficient cooling for the processing material, so that the maximum temperature change of the material in the grinding zone during operation reaches 10 to 20 °, so that Make the polishing process unstable. As a result, most of the elongated mass material thus obtained is in the form of incompletely polished coarse particles consisting of a large amount of small particles that are fixed or fused together or separated. This reduces the output of the device and further increases the total energy consumption.
    [1] FIELD OF THE INVENTION The present invention relates to the field of processing polymeric materials, and in particular to methods and apparatus for producing powders from polymeric materials, which can be applied, for example, in the polishing of polymeric materials reinforced with high strength fibers and metal wires in their subsequent application. have.
    [57] 1 is a diagram showing a cross section of a device according to the invention in which a shear stress modulator is installed between a compression screw and a rotor and designed in a right-sided polyhedral prism shape.
    [58] 2 shows a cross section of the device according to the invention with a shear stress modulator installed on the inner surface of the casing;
    [59] 3 includes a shear stress modulator consisting of two members, the first member of which is disposed between the compression screw and the rotor and the second member of which is disposed on the inner surface of the casing on the surface of the first member. Diagram showing the cross section of the device according to.
    [60] 4 includes a shear stress modulator consisting of two members, the first member being disposed between the compression screw and the rotor and the second member partially and over the surface of the first member of the shear stress modulator. Diagram showing a cross section of the device according to the invention, which is disposed on the inner surface of the casing, partially on the surface.
    [61] 5 shows various embodiments of a shear stress modulator seen in cross section orthogonal to the modulator axis coincident with the axis of rotation of the rotor, FIGS. 5A, 5B and 5C being installed between the compression screw and the rotor; Shear stress modulators (or first members thereof) each designed in a rotor shape, an elliptical cylinder shape and a rectangular polyhedral shape having longitudinal grooves on the side thereof are shown, and FIG. 5D shows a shear stress modulator (or A second member of the shear stress modulator) is shown.
    [62] * Description of the symbols for the main parts of the drawings *
    [63] 1: casing
    [64] 2: charging opening
    [65] 3: discharging opening
    [66] 4: compacting (densification) zone
    [67] 5: compacting screw
    [68] 6: grinding zone
    [69] 7: shear stress modulator disposed between the compression screw and the rotor
    [70] 8: rotor
    [71] 9: ring-shaped slot
    [72] 10: annular clearance
    [73] 11: Means for cooling the casing in compressed (grinded) and abrasive zones
    [74] 12: compression screw cooling means
    [75] 13: shear stress modulator cooling means
    [76] 14: rotor cooling means
    [77] 15: shear stress modulator disposed on the inner surface of the casing in the grinding zone
    [78] 16: first member of the shear stress modulator
    [79] 17: second member of the shear stress modulator
    [11] It is an object of the present invention to provide a method of processing a polymeric material with high efficiency which reduces the energy consumption and expands the range of polishable objects under conditions in which pressure and shear stresses simultaneously act, and an apparatus for carrying out the method.
    [12] This object of the present invention is achieved by using a polymer material processing method comprising the step of compressing the material and the subsequent acting of the shear stress under certain pressure conditions. According to the invention, squeezing is achieved at a pressure of 0.7 to 100 MPa, said subsequent action being caused by shear stress modulated with an amplitude having a frequency between 0.3 and 1000 Hz and a modulation depth between 0.05 and 1 Is performed. The maximum shear stress value is in the range of 1 to 50 N / mm 2, and the subsequent action by the compressive and amplitude modulated shear stress is applied to the material upon cooling.
    [13] The object of the present invention also includes a cylindrical casing having a charging opening and a discharging opening, inside the casing a helical groove on its surface in a compacting zone. ) Is arranged with a compacting screw arranged therein, and within the grinding zone is a rotor designed in the shape of a rotating body and mounted coaxially with the inner surface of the casing. This is achieved by applying an apparatus for producing powder from a polymer material, which is arranged in a straight line with the compression screw rotatably in an annular clearance with respect to the inner surface. The apparatus is provided with cooling means for cooling the casing and / or the rotor in the grinding zone. According to the invention, the apparatus is further provided with a shear stress modulator disposed between the compression screw and the rotor or on the inner surface of the casing in the abrasive zone.
    [14] In such a device, the shear stress modulator is a structural member in which the shear stress value applied to the processing material by the shear stress modulator is varied at regular time intervals. This variation of the shear stress value is carried out by certain parameters: modulation frequency, maximum shear stress value and modulation depth.
    [15] The shear stress modulator, which is installed between the compression screw and the rotor, is designed in the form of an elliptical cylinder with a short height, the axis of which passes through its center of gravity parallel to the cylinder's busbar If the shear stress modulator is designed in the form of a right polyhedral prism, or the shear stress modulator is designed in the form of a right polyhedral prism, then the axis through the center of gravity parallel to the edge of the prism coincides with the axis of rotation of the rotor. Or a shear stress modulator designed in the form of a rotor with longitudinal and / or inclined recesses arranged on its side, the rotor having its axis of rotation coincident with the axis of rotation of the rotor. Is arranged to. Accordingly, the shear stress modulator is rotatably mounted in a state of forming a ring-shaped slot with respect to the inner surface of the casing.
    [16] The shear stress modulator disposed on the inner surface of the casing is designed in the form of a short, ring-shaped protrusion, on which the longitudinal and / or inclined recesses are arranged. Further, the ridge is provided in a state of forming a ring-shaped slot with respect to the surface of the rotor.
    [17] If the shear stress modulator is disposed at any of the locations described above, the width of that narrow section of the ring-shaped slot is equivalent to 10 to 90% of the width of the annular gap.
    [18] In addition, cooling means for the casing and / or for the compression screw in the compression zone are further provided.
    [19] The width of the narrow section of the ring-shaped slot is the term used in connection with the area where the width of the ring-shaped slot is minimal.
    [20] In the design of a shear stress modulator as a short height body, the height is the term used in relation to the total length of the body along the rotor axis.
    [21] The short height of the body is the term used in connection with the case where the diameter of the compression screw is more than twice the height of the body.
    [22] In particular, in the design of the device of the present invention, the ratio of the height of the shear stress modulator to the diameter of the compression screw can be equal to 0.01 to 0.5 to 1.
    [23] According to an embodiment of a device in which the shear stress modulator is disposed between the compression screw and the rotor, and the shear stress modulator has a rotor shape, the rotor can be designed as a disk or truncated ellipsoid, According to an embodiment of the device having an elliptical cylinder or rectangular polyhedral prism shape, longitudinal and / or inclined recesses may be arranged on the side of the prism.
    [24] In the design of a shear stress modulator in the form of a rotor, longitudinal recess is the term used in connection with a recess whose axis extends along the axis of rotation of the rotor. In the design of a shear stress modulator in the form of an elliptical cylinder, longitudinal recess is the term used in connection with a recess having an axis extending along an axis passing through its center of gravity parallel to the busbar of the cylinder. In the design of a shear stress modulator in the form of a right-sided polyhedral prism, a longitudinal recess is a term used in connection with a recess having an axis extending along an axis passing through its center of gravity parallel to the edge of the prism.
    [25] Inclined recess is a term used in connection with a recess having an axis extending obliquely to the aforementioned axis. These inclined recesses can be arranged at an inclination of 0.1 to 89 °, the depth of the recess not exceeding five times the width of the ring shaped slot.
    [26] In addition to the above-mentioned inclined recesses, further inclined recesses may be arranged on the side of the elliptical cylinder, the rotating body or the right-sided polyhedral prism, and the inclination of the further recess is the slope of the above-mentioned inclined recess. Different from the slope, these recesses are all crossing repeatedly.
    [27] According to an embodiment of the device in which the shear stress modulator is disposed between the compression screw and the rotor and has the shape of a polyhedral prism, the outer edge of the prism can be designed as a rounded edge, for example, rounded. The radius of the portion may reach 0.3 to 5 mm. In an embodiment of an apparatus comprising an elliptical cylindrical shear stress modulator, the length of the short axis of the cylinder cross section may be equal to the diameter of the rotor, and the length of the longer axis of the cross section is equal to the width of the annular gap. It can be equal to the sum of the electron diameters.
    [28] In particular, the shear stress modulator may be further provided with cooling means.
    [29] In the design of a shear stress modulator located on the inner surface of the casing in the form of a ring-shaped ridge, longitudinal and / or inclined recesses are arranged on the surface of the ridge. Longitudinal recess is here a term used in connection with a recess whose axis is guided along the axis of the casing, and inclined recess is a term used in connection with a recess having an axis extending obliquely to the axis of the casing. The inclined recesses can be arranged at a slope of 0.1 to 89 °, the depth of which does not exceed five times the width of the ring shaped slot.
    [30] In particular, kneading pins and / or plates may be arranged on the sides of the rotor, or spiral grooves may be arranged on the sides of the rotor to facilitate the transport of material to the casing outlet.
    [31] According to an embodiment of the device in which the shear stress modulator is disposed between the compression screw and the rotor, the modulator may be installed to be able to rotate separately or in cooperation with the rotor and / or the compression screw.
    [32] In particular, the ring shaped ridges can be designed to be rectangular, triangular or trapezoidal.
    [33] In particular, in the apparatus, the casing cooling means in the compression zone and the casing cooling means in the grinding zone can be designed to operate in a cooperative manner as the casing cooling means in the compression zone and the grinding zone.
    [34] The object of the present invention also includes a cylindrical casing having an inlet and an outlet, inside of which is arranged a compression screw in which a spiral groove is arranged on its surface in a compression zone, in the shape of a rotating body in the grinding zone. A rotor is designed and arranged coaxially with the inner surface of the casing, the rotor producing powder from a polymeric material, which is disposed in a straight line with the compression screw rotatably in an annular gap with respect to the inner surface of the casing. It is achieved by applying a device for. The apparatus is provided with cooling means for cooling the casing and / or the rotor in the grinding zone. According to the invention, the apparatus is further provided with a shear stress modulator consisting of two members mounted inside the grinding zone. The first member of the shear stress modulator is disposed between the compression screw and the rotor, and the second member is disposed on the inner surface of the casing. The first member of the shear stress modulator is designed in the shape of an elliptical cylinder with a short height, which cylinder is arranged such that its axis penetrating its center of gravity parallel to the cylinder's busbar coincides with the axis of rotation of the rotor, or the shear stress If the modulator is designed in the form of a right-sided polyhedral prism, the prism is arranged such that its axis penetrating its center of gravity parallel to the edge of the prism coincides with the axis of rotation of the rotor, or the shear stress modulator is longitudinally If designed in the form of a rotor with inclined recesses arranged, the rotor is arranged such that its axis of rotation coincides with the axis of rotation of the rotor. The first member of the modulator is rotatably mounted in the form of a ring-shaped slot with respect to the inner surface of the casing or with respect to the surface of the second member of the shear stress modulator. The second member of the shear stress modulator is designed in the form of a low-profile ring shaped ridge, wherein longitudinal and / or inclined recesses are arranged on the surface of the ridge, and the ring with respect to the surface of the first member of the shear stress modulator. It is mounted in a state of forming a shape slot. The width of that narrow section of the ring shaped slot is equal to 10 to 90 percent of the width of the annular gap. The densification zone and / or the compression screw of the casing of the device are further provided with cooling means.
    [35] In the design of a shear stress modulator member as a low height body, its height is the term used in relation to the total length of the body along the rotor axis (or the axis of the device).
    [36] Lower height body is a term used in connection with the body height where the diameter of the compression screw does not exceed twice the height of the body.
    [37] In particular, in such a device, the second member of the shear stress modulator may be disposed directly above the first member surface of the shear stress modulator, or some may be disposed above the first member surface of the shear stress modulator and the other may be disposed above the rotor surface. Can be. Positioning the second member of the shear stress modulator on the surface of the first member of the shear stress modulator means that the rotor axis is such that the center of gravity of the second member of the shear stress modulator penetrates the center of gravity of the first member of the modulator. It is located on a plane orthogonal to. The fact that the second member of the shear stress modulator is partly above the surface of the first member of the shear stress modulator and the other part is above the rotor surface indicates that the center of gravity of the second member of the shear stress modulator is from the plane towards the outlet. For example, it means that it is located at a distance less than the sum of the half height of the first and second member body. The aforementioned displacement may be, for example, equal to 0.1 to 1 of the sum.
    [38] The width of that narrow section of the ring shaped slot is the term used in relation to the minimum distance between the surface of the first member of the shear stress modulator and the inner surface of the second member.
    [39] In particular, in such an apparatus, the ratio of the sum of the half heights of the members of the shear stress modulator to the compression screw diameter may be equal to 0.01 to 0.5 to 1.
    [40] If the first member of the shear stress modulator has a rotor shape, this rotor may be designed, for example, as a disk or truncated ellipsoid.
    [41] If the first member of the shear stress modulator has the shape of an elliptical cylinder or a right-sided polyhedral prism, longitudinal and / or inclined recesses may be arranged on the side of the cylinder or prism.
    [42] In the design of a first member of a shear stress modulator in the form of a rotor, longitudinal recess is the term used in connection with a recess whose axis extends along the axis of rotation of the rotor. In the design of a first member of a shear stress modulator in the form of an elliptical cylinder, longitudinal recess is a term used in connection with a recess having an axis extending along an axis passing through its center of gravity parallel to the cylinder busbar. . In the design of a first member of a shear stress modulator in the form of a right-sided polyhedral prism, the longitudinal recess is a term used in connection with a recess having an axis extending along its axis parallel to the edge of the prism. .
    [43] Inclined recess is a term used in connection with a recess having an axis extending obliquely to the aforementioned axis. These inclined recesses can be arranged at an inclination of 0.1 to 89 °, the depth of the recess not exceeding five times the width of the ring shaped slot.
    [44] In addition to the above-mentioned inclined recesses, further inclined recesses may be arranged on the side of the elliptical cylinder, the rotating body or the right-sided polyhedral prism, and the inclination of the further recess is the slope of the above-mentioned inclined recess. Different from the slope, these recesses are all crossing repeatedly.
    [45] According to an embodiment of the device in which the first member of the shear stress modulator has the shape of a polyhedral prism, the outer edge of the prism can in particular be designed as a rounded edge, for example the radius of the rounded portion. This can range from 0.3 to 5 mm.
    [46] In particular, according to an embodiment of the device in which the first member of the shear stress modulator is designed in an elliptical cylinder shape, the length of the short axis of the cylinder cross section can be equal to the diameter of the rotor, and the length of the longer axis of the cylinder cross section is It can be equal to the sum of the width of the annular gap and the rotor diameter.
    [47] In particular, the first and / or second member of the shear stress modulator may be further provided with cooling means.
    [48] In particular, the ring-shaped ridge can be designed to be rectangular or trapezoidal.
    [49] In particular, in such an apparatus, the casing cooling means in the densification zone and the casing cooling means in the grinding zone may be designed to operate in a cooperative relationship as the casing cooling means in the densification zone and the grinding zone.
    [50] Embodiments of an elliptical cylindrical shape shear stress modulator (or first member of a modulator of a variant of the device) are preferred for the treatment of reinforced tire scrap using only synthetic cords. For the processing and polishing of scrap tires reinforced with metal and synthetic cords, an embodiment of a rotor-shaped shear stress modulator (or first member of the modulator) is provided with longitudinal and / or inclined recesses arranged on its side. It is preferable. Embodiments of a rectangular polyhedral prism-shaped shear stress modulator (or a first member of a modulator of a variant of the apparatus) are desirable not only for the treatment of scrap of drive rubber belts but also for the treatment of scrap of industrial rubber articles with extremely high content of synthetic cords. Do.
    [51] By varying the width of that narrow section of the ring-shaped slot, the shear stress generated inside this slot can be increased many times compared to the shear stress generated inside the annular gap, and thus from the most efficient decomposition, reinforcement elements of the polymeric material. Separation of the polymer material, reduction of energy consumption, and increased productivity of the device are achieved.
    [52] The ratio of the height of the shear stress modulator (or the first member of the modulator of the variant of the apparatus) to the diameter of the compression screw only varies within the range of 0.01 to 0.25 to 1, thereby the average of the polymer particles produced as well as the particles of the synthetic and metal cords. Size and shape may be affected.
    [53] Embodiments of the treatment apparatus for polymer materials according to any one of the foregoing descriptions provide for the realization of compression of the material upon cooling and the subsequent action of shear stress modulated with amplitude under certain pressure conditions upon cooling.
    [54] Thus, when the treatment of the polymer material is carried out using the method according to the invention, the action exerted on the polymer material by the shear stress modulated in amplitude under the predetermined pressure and cooling conditions may lead to the initiation of the decomposition process of the material which is already compressed. This decomposition process begins when the shear stress reaches its maximum. The combined action of the aforementioned factors results in a highly efficient decomposition process, which can form fine powders containing fine polymer particles and, in particular cases, also containing broken reinforcing fiber fragments and wire fragments. Under the action of the amplitude modulated shear stress, it is significant that the twisted fibers of the synthetic cord quickly decompose into filaments having a thickness of about 0.01 to 0.1 mm, i.e., the deformation of the bouff of the synthetic cord proceeds rapidly.
    [55] As described above, the present invention has novelty as compared to the prior art closest to the present invention, and it can be seen that the present invention is inventive because of the configuration features not presented or implied in the prior art.
    [56] An interim examination of the method and apparatus according to the present invention shows that the present invention has a wide industrial applicability.
    [80] The polymer material processing apparatus shown in FIG. 1 includes a casing 1 having an inlet 2 and an outlet 3. Inside the casing 1, a compression screw 5 with spiral grooves arranged on its surface is arranged in the compression zone 4, and a shear stress modulator 7 and a rotor 8 in the grinding zone 6. ) Is arranged. The shear stress modulator 7 is designed in the shape of a right-sided polyhedral prism and is provided to form a ring-shaped slot 9 with respect to the inner surface of the casing. The rotor 8 is provided to form an annular gap 10 with respect to the inner surface of the casing. The compression screw 5 and the rotor 8 are mounted in line with each other, and an axis parallel to the edge of the rectangular polyhedral prism and penetrating the center of gravity coincides with the axis of rotation of the rotor. This polymer material processing apparatus is provided with casing cooling means 11, compression screw cooling means 12, shear stress modulator cooling means 13, and rotor cooling means 14 in its compression zone and abrasive zone.
    [81] The polymer material processing apparatus shown in FIG. 2 comprises a casing 1 with an inlet 2 and an outlet 3. Inside the casing 1, a compression screw 5 is arranged in the compression zone 4 with spiral grooves arranged on its surface, and in the grinding zone 6 a rotor 8 with respect to the inner surface of the casing. The annular gap 10 is provided while being mounted in line with the compression screw 5. A shear stress modulator 15 designed as a ring-shaped ridge on the inner surface of the casing is disposed inside the grinding zone 6, and longitudinal recesses are arranged on the surface of the ridge. A ring-shaped slot 9 is formed between the shear stress modulator 15 and the surface of the rotor 8. This polymer material processing apparatus is also provided with cooling means 11, compression screw cooling means 12, and rotor cooling means 14 in the compression zone and the abrasive zone.
    [82] The polymer material processing apparatus shown in FIG. 3 comprises a casing 1 with an inlet 2 and an outlet 3. Inside the casing 1, a compression screw 5 is arranged in the compression zone 4 with spiral grooves arranged on its surface, and in the grinding zone 6 a shear stress modulator designed in the form of an elliptical cylinder. 1 member 16 and the rotor 8 are arrange | positioned. Within the polishing zone 6, a second member 17 of the shear stress modulator is also arranged on the inner surface of the casing on the surface of the first member 16 of the shear stress modulator. This second member is designed as a ring-shaped ridge with longitudinal recesses arranged on its surface. A ring-shaped slot 9 is formed between the first member 16 and the second member 17 of the shear stress modulator. The rotor 8 is provided to form an annular gap 10 with respect to the inner surface of the casing. The compression screw 5 and the rotor 8 are mounted in line with each other, and the axis of the elliptical cylinder which is parallel to the cylinder busbar and penetrates the center of gravity thereof coincides with the rotation axis of the rotor. This polymer material processing apparatus is also provided with casing cooling means 11, compression screw cooling means 12, shear stress modulator cooling means 13 and rotor cooling means 14 in the compression zone and the abrasive zone.
    [83] The polymer material processing apparatus shown in FIG. 4 comprises a casing 1 with an inlet 2 and an outlet 3. Inside the casing 1, a compression screw 5 is arranged in the compression zone 4 with spiral grooves arranged on its surface, and in the polishing zone 6 longitudinal recesses are arranged on its side. The first member and the rotor 8 of the shear stress modulator designed in the form of a disk are arranged. In the polishing zone 6, the second member 17 of the shear stress modulator is disposed on the inner surface of the casing. The second member of this shear stress modulator is designed as a ring-shaped ridge with longitudinal recesses arranged on its surface. The second member 17 of the shear stress modulator is partly disposed on the surface of the first member and partly on the surface of the rotor. The first member 16 and the second member 17 of the modulator are installed such that a ring-shaped slot 9 is formed therebetween, and the rotor 8 opens the annular gap 10 with respect to the inner surface of the casing. It is installed to form. The compression screw 5 and the rotor 8 are mounted in line with each other, and the axis of rotation of the first member 16 coincides with the axis of rotation of the rotor. This polymer material processing apparatus also includes casing cooling means 11, compression screw cooling means 12, first member cooling means 13 of the shear stress modulator and rotor cooling means 14 in its compression zone and abrasive zone. Is provided.
    [84] The polymer material processing apparatus shown in FIG. 1 operates in the manner described below.
    [85] Tires reinforced with synthetic and metal cords in the form of pieces to be polished, ie in the form of pieces of average size of about 30 x 30 x 20 mm, are continuously filled into the inlet 2 of the casing 1. The material sent to the densified zone 4 is captured by the helical groove of the compression screw 5, cooled and gradually compressed at the same time, and then conveyed towards the shear stress modulator 7. The cooling of the device is carried out by supplying a liquid coolant into the casing cooling means 11, the compression screw cooling means 12, the shear stress modulator cooling means 13 and the rotor cooling means 14. Immediately above the shear stress modulator 7, a dense layer made of the treated material is formed inside the ring-shaped slot 9 formed between the shear stress modulator 7 and the inner surface of the casing 1. Under predetermined pressure and cooling conditions, the application of amplitude modulated shear stress to this dense layer causes the material to break down and degrade gradually within the ring-shaped slot 9 as the material enters the abrasive zone 6. To start. This process is most active in the vicinity of the various inclusions present in the tire pieces, especially the small metal wire and synthetic cord fiber pieces that become stress concentrators. As a result, the rubber breaks down into smaller fragments while the rubber quickly separates from the synthetic and metal cords. Thereafter, in the annular gap 10 formed between the casing 1 and the rotor 8, a synthetic fiber baffle produced from fine rubber powder, a piece of metal-free metal wire, and broken synthetic cord fibers. By this formation, the decomposition treatment of the material is completed. While gradually moving forwards toward the outlet 3 along the inside of the annular gap 10, the mixture of rubber powder, wire flakes and synthetic fiber baffles is cooled and released out of the outlet 3, at which time the temperature of the material Is 30-40 degreeC. This mixture can then be easily separated into the main components (rubber powder, metal wire, short synthetic cord fibers or baffles) by magnetic and vibration-pneumatic separation methods.
    [86] The processing apparatus of the polymer material shown in FIG. 2 also operates in a similar manner as the apparatus shown in FIG.
    [87] The processing apparatus for the polymer material shown in FIG. 3 is operated in the manner described below.
    [88] The material to be polished, ie tires reinforced with synthetic and metal cords in the form of pieces having an average size of about 30 x 30 x 20 mm, is continuously filled into the inlet 2 of the casing 1. The material sent to the densification zone 4 is captured by the helical grooves of the compression screw 5, cooled and gradually compressed at the same time, and then by the first and second members 16 and 17 of the shear stress modulator. It is conveyed toward the formed ring-shaped slot 9. The cooling of the device is carried out by supplying a liquid coolant into the casing cooling means 11, the compression screw cooling means 12, the first member cooling means 13 of the shear stress modulator and the rotor cooling means 14. A dense layer of treated material is formed inside the ring-shaped slot 9 just above the first member 16 and the second member 17 of the shear stress modulator. Under certain pressure and cooling conditions, the application of amplitude modulated shear stress to a layer of material causes the material to gradually break up and begin to degrade within the ring-shaped slot 9 as the material enters the abrasive zone 6. . This process is most active in the vicinity of the various inclusions present in the tire pieces, especially the small metal wire and synthetic cord fiber pieces that become stress concentrators. As a result, the rubber breaks down into smaller fragments while the rubber quickly separates from the synthetic and metal cords. Thereafter, in the annular gap 10 formed between the casing 1 and the rotor 8, a fine fiber powder, a piece of non-rubber metal wire, and a synthetic fiber baffle produced from broken synthetic cord fibers By this formation, the decomposition treatment of the material is completed. The mixture of rubber powder, wire flakes and synthetic fiber baffles is cooled and discharged out of the outlet 3 while gradually moving forward along the inside of the annular gap 10 toward the outlet 3, at which time the temperature of the material 30 to 40 ° C. This mixture can then be easily separated into the main components (rubber powder, metal wire, short synthetic cord fibers or baffles) by magnetic and vibration-pneumatic separation methods.
    [89] The processing apparatus of the polymer material shown in FIG. 4 also operates in a similar manner as the apparatus shown in FIG.
    [90] According to the invention, a method for producing powder from a reinforced industrial rubber article and an apparatus for realizing it can be illustrated by the examples below.
    [91] Example 1
    [92] Scrap rubber with fabric cords cut into pieces of approximately 20 x 20 x 10 mm size was filled through the inlet into the polymeric material processing apparatus (in which the shear stress modulator was in the form of an oval cylinder as shown in Figure 5b). Except as designed, the apparatus shown schematically in FIG. 1 was used). The material was first compressed and simultaneously cooled under a pressure of 0.7 MPa, and then modulated shear stress was applied to an amplitude having a modulation depth of about 0.3 and a frequency of 3 Hz. The maximum shear stress value under these conditions was 1.0 N / mm 2. The cooling of the material was carried out by supplying liquid coolant fluid (water) with an initial temperature of 15 ° through the cooling channels arranged along the walls of the casing into the compression screw, shear stress modulator and rotor.
    [93] The mixture thus obtained consists of fabric cord fragments, ie baffles (fiber length 2-20 mm) and rubber powder. This mixture was separated by vibration-pneumatic separation treatment. The rubber powder obtained after sieving using a sieve having a screen size of 1 mm provided a residue of about 35 wt.%, Of which the rubber bonded to the cord gave 2.5 wt.% Of the total amount of the residue. Occupied. Thus, productivity was 31 kg / h and the energy consumption for polishing was 0.45 kW.h / kg.
    [94] Example 2 through Example 9
    [95] The processing was performed as in Example 1.
    [96] The schematic description of the device for all examples, the type of shear stress modulator, the parameters of the treatment method (pressure, maximum shear stress value, modulation frequency and depth), the characteristics of the powder produced, the productivity and the energy consumption rate are shown in the table. Listed.
    [97] Fabric cord debris, ie the resulting mixture consisting of baffles and rubber powder, were separated by vibration-pneumatic separation treatment.
    [98] Example 10
    [99] Polishing was carried out according to the method disclosed in the invention USSR N 1434663. The parameters of the treatment method and the characteristics of the powder produced are listed in the table.
    [100] Example 11-16
    [101] The treatment method was performed as in Example 1 except that the material to be polished was aircraft tire scrap.
    [102] The table outlines the device for all examples, the type of shear stress modulator, the parameters of the treatment method (pressure, maximum shear stress value, modulation frequency and depth), the characteristics of the powder produced, the productivity and the energy consumption. Enumerated.
    [103] Cord fragments, ie the resulting mixture consisting of baffles and rubber powder, were separated by vibration-pneumatic separation treatment.
    [104] Example 17
    [105] Polishing was performed according to the method disclosed in invention USSR N 1434663. The parameters of the treatment method and the characteristics of the powder produced are listed in the table.
    [106] Example 18-23
    [107] The treatment method was carried out as in Example 1 except that the material to be polished was a rubber containing metal and fabric cords.
    [108] The schematic description of the device for all examples, the type of shear stress modulator, the parameters of the treatment method (pressure, maximum shear stress value, modulation frequency and depth), the characteristics of the powder produced, the productivity and the energy consumption rate are shown in the table. Enumerated.
    [109] The resulting mixture consisting of cord fragments, ie pieces 3-15 mm in length, fabric cord fiber fragments, ie baffles and rubber powder, was separated by magnetic separation and subsequent vibration-pneumatic separation.
    [110] Example 24 and Example 25
    [111] Polishing was carried out according to the method disclosed in the invention USSR N 1434663 and the apparatus disclosed in the Russian Federation Patent No. N 2057013. The parameters of the treatment method and the characteristics of the powder produced are listed in the table.
    [112] Example 26, Example 28, Example 30, Example 32, Example 34
    [113] The processing method was performed as in Example 1.
    [114] The schematic description of the device for all examples, the material, the type of shear stress modulator, the parameters of the treatment method (pressure, maximum shear stress value, modulation frequency and depth), the characteristics of the powder produced, the productivity, the energy consumption rate, etc. Listed in the table.
    [115] Example 27, Example 29, Example 31, Example 33, Example 35
    [116] Polishing was carried out according to the apparatus disclosed in Russian Federation Patent No. 2057013. The parameters of the treatment method and the characteristics of the powder produced are listed in the table.
    [117] Therefore, according to the method and apparatus (in all the embodiments described above) according to the present invention, the production of powder from the polymer material can reduce the energy consumption while increasing its productivity. In addition, high-quality powders can be produced from the first polymer and polymer wastes, and also from polymeric materials reinforced with high strength fibers and metal wires, in particular extending the area of the treatable articles, while simultaneously separating the polymer from the reinforcing fibers and metal wires. You can expand the range.
    [118] It is to be understood that the spirit of the invention shown and described herein is to be taken in accordance with the preferred embodiments, and that various changes may be made without departing from the scope of the claims or the invention that follows.
    [119] Example NDiagram of the deviceTypes of modulators a, b, c, d according to FIG. 5materialPressureShear stress value N / mm2Modulation Frequency of Shear Stress HzModulation depthProductivity kg / hPolishing energy consumption rate kW.h / kgCharacteristics of Abrasive MaterialsRubber residues bonded to the cord wt.%Rpm Mesh size of the sieve mmResidue wt.% Of the sieve One234567891011121314 OneFig. 1bRubber scrap with fabric cord0.71.030.3310.451.0352.590 2Fig. 1a"20101500.2500.481.0251.430 3Fig. 1c"30307.50.05610.381.0150.290 4Fig. 1b"50400.30.8350.531.0360.5310 5Fig. 2d"40505000.3600.421.0220.21100 6Fig. 4a + d"253510000.63560.431.0200.18100 7Fig. 1a"3725500.6530.51.0260.5100 8Fig. 1c"31320.5One600.391.0240.960 9Fig. 4c + d"25305000.5650.471.0180.3590 10According to example 7 of inventive agent N 1434663"0.75--150.611.0566.7- 11Fig. 1aAircraft tire scrap35451500.1540.71.0281.530 12Fig. 1c"25352.50.6420.51.0210.930 13Fig. 1b"252030.4500.61.035390 14Fig. 1a"40453000.2670.451.0211.560 15Fig. 2d"45303000.8690.441.0170.560 16Fig. 4b + d"40304.00.6720.421.0150.4120 17In accordance with inventive agent N 1434663"252.0--311.21.04512-
    [120] Example NDiagram of the deviceTypes of modulators a, b, c, d according to FIG. 5materialPressureShear stress value N / mm2Modulation Frequency of Shear Stress HzModulation depthProductivity kg / hPolishing energy consumption rate kW.h / kgCharacteristics of Abrasive MaterialsRubber residues bonded to the cord wt.%Rpm Mesh size of the sieve mmResidue wt.% Of the sieve One234567891011121314 18Fig. 2dTire rubber with metal and fabric cord20355000.8980.411.0300.55120 19Fig. 3a + d"25404500.51040.321.0350.4590 20Fig. 1a"44261500.25950.41.0430.630 21Fig. 1b"324540.4750.451.0351.5120 22Fig. 1c"1.524100.6410.621.0561.8120 23Fig. 1a"15183000.7870.421.0482.160 24In accordance with invention additive N 1434663"15185 minutes after processing starts, processing fails due to screw damage 25Apparatus according to Russian Federation Patent No. 2057013"1518--281.051.0519.090
    [121] Example NDiagram of the deviceTypes of modulators a, b, c, d according to FIG. 5materialPressureShear stress value N / mm2Modulation Frequency of Shear Stress HzModulation depthProductivity kg / hPolishing energy consumption rate kW.h / kgCharacteristics of Abrasive MaterialsRubber residues bonded to the cord wt.%Rpm Mesh size of the sieve mmResidue wt.% Of the sieve One234567891011121314 26Fig. 1bScrap of ethylene-propylene rubber202550.8850.350.6311-90 27Apparatus according to Russian Federation Patent No. 2057013"1815--450.510.6323-90 28Fig. 2dNatural leather waste2540150One180.551.03-90 29Apparatus according to Russian Federation Patent No. 2057013"2521--80.911.012-90 30Fig. 2dPaper laminated by LDPE 10wt.%25451500.6110.80.6318-90
    [122] Example NDiagram of the deviceTypes of modulators a, b, c, d according to FIG. 5materialPressureShear stress value N / mm2Modulation Frequency of Shear Stress HzModulation depthProductivity kg / hPolishing energy consumption rate kW.h / kgCharacteristics of Abrasive MaterialsRubber residues bonded to the cord wt.%Rpm Mesh size of the sieve mmResidue wt.% Of the sieve One234567891011121314 31Apparatus according to Russian Federation Patent No. 2057013"2330--No powder is produced90 32Fig. 3a + dCarbon fiber waste100504500.4150.60.47.5-90 33Apparatus according to Russian Federation Patent No. 2057013"10040--4.50.950.415-90 34Fig. 3a + dOrganic plastic waste50484500.4210.70.410-90 35Apparatus according to Russian Federation Patent No. 2057013"5045--7.51.20.423-90
    [123] FIELD OF THE INVENTION The present invention relates to methods and apparatus for producing powders from polymeric materials and can be used in the field of polymer processing.
    权利要求:
    Claims (24)
    [1" claim-type="Currently amended] A method of processing a polymeric material comprising the step of compacting a material and subsequent action of shear stress under a predetermined pressure condition, the method comprising:
    Compression of the material is achieved at a pressure of 0.7 to 100 MPa and the subsequent action is performed by a shear stress modulated with an amplitude having a frequency of 0.3 to 1000 Hz and a modulation depth of between 0.05 and 1, the maximum shear stress value being And a subsequent action by said compressive and amplitude modulated shear stresses being applied to the material upon cooling.
    [2" claim-type="Currently amended] A cylindrical casing (1) having an inlet (2) and an outlet (3), inside the casing is arranged a compression screw (5) in which a spiral groove is arranged on its surface in the compression zone (4), In the grinding zone 6, a rotor 8 designed in the shape of a rotor and mounted coaxially with the inner surface of the casing 1 is arranged, the rotor forming an annular gap 10 with respect to the inner surface of the casing. In the polymer material processing apparatus which is arranged in a line with the compression screw (5) rotatably in a state of being made, and provided with cooling means for cooling the casing and / or the rotor (8) in the grinding zone (6). ,
    Shear stress modulators 7, 15 are additionally provided between the compression screw 5 and the rotor 8 or on the inner surface of the casing 1 in the grinding zone 6, and the compression screw 5 The shear stress modulator 7 provided between the rotor and the rotor 8 is designed in the form of an elliptical cylinder with a short height, the axis of which penetrates the center of gravity parallel to the cylinder's busbar and the rotor 8 When the shear stress modulator is designed in the form of a right-sided polyhedral prism, the prism has an axis that passes through its center of gravity parallel to the edge of the prism and the rotational axis of the rotor (8). If the shear stress modulator is designed in the form of a rotating body with longitudinal and / or inclined recesses arranged on its side, the rotating body has a rotational axis whose rotational axis corresponds to that of the rotor 8. According The shear stress modulator 7 is rotatably mounted in a state of forming a ring-shaped slot 9 with respect to an inner surface of the casing 1, and a shear disposed on an inner surface of the casing 1; The stress modulator 15 is designed in the form of a low-profile ring-shaped ridge with longitudinal and / or inclined recesses arranged on its surface, which ring-shaped ridge is ring-shaped relative to the surface of the rotor 8. Mounted in the form of a slot 9, the width of its narrow section of the ring-shaped slot 9 equals 10 to 90% of the width of the annular gap 10, the apparatus having compression screw cooling means (12) and / or casing cooling means in the compression zone (4) are further provided.
    [3" claim-type="Currently amended] The apparatus of claim 2, wherein the ratio of the height of the shear stress modulator (7, 15) to the diameter of the compression screw (5) is 0.01 to 0.5 to 1.
    [4" claim-type="Currently amended] The apparatus of claim 2, wherein the rotating body of the shear stress modulator (7) has a disc or truncated ellipsoid shape.
    [5" claim-type="Currently amended] The apparatus of claim 2, wherein the longitudinal and / or inclined recesses are arranged on the side of an elliptical cylinder or a right-sided polyhedral prism.
    [6" claim-type="Currently amended] The length of the short axis of the cross section of the elliptical cylinder is equal to the diameter of the rotor (8), the length of the long axis of the cross section of the diameter of the rotor (8) and the width of the annular gap (10). A polymer material processing apparatus, such as a sum.
    [7" claim-type="Currently amended] 3. Apparatus according to claim 2, characterized in that the shear stress modulator (7) is further provided with cooling means (13).
    [8" claim-type="Currently amended] 3. The apparatus of claim 2, wherein the kneading pins and / or plates are arranged on the side of the rotor. 8.
    [9" claim-type="Currently amended] 3. Apparatus according to claim 2, characterized in that the spiral grooves which facilitate the transport of material to the outlet (3) are arranged on the side of the rotor (8).
    [10" claim-type="Currently amended] 3. The shear stress modulator (7) according to claim 2, arranged between the compression screw (5) and the rotor (8), separately or in cooperation with the rotor (8) and / or the compression screw (5). Polymer material processing apparatus, characterized in that the rotatable installation.
    [11" claim-type="Currently amended] The apparatus of claim 2, wherein the ring-shaped ridge is designed to be rectangular or trapezoidal.
    [12" claim-type="Currently amended] The device according to claim 2, wherein the means for cooling the casing in the compression zone 4 and the means for cooling the casing in the grinding zone 6 cooperate with the means 11 for cooling the casing in the compression zone and the grinding zone. Polymer material processing apparatus characterized in that it is designed to operate in a relationship.
    [13" claim-type="Currently amended] A cylindrical casing (1) having an inlet (2) and an outlet (3), in the interior of which is arranged a compression screw (5) with a spiral groove arranged on its surface in the compression zone (4), and Within the zone 6 is arranged a rotor 8 designed in the shape of a rotor and coaxially mounted with the inner surface of the casing, the rotor rotating with forming an annular gap 10 with respect to the inner surface of the casing. A polymer material processing apparatus, possibly arranged in line with the compression screw 5 and provided with cooling means 14 for cooling the casing and / or the rotor 8 in the polishing zone 6,
    In addition, a shear stress modulator consisting of two members is further provided inside the abrasive zone 6, and the first member 16 of the shear stress modulator is disposed between the compression screw 5 and the rotor 8, The second member 17 of the shear stress modulator is arranged on the inner surface of the casing 1, and the first member 16 of the shear stress modulator is designed in the form of an elliptical cylinder of short height, the cylinder busbar of the cylinder. If the axis penetrating the center of gravity parallel to the axis is arranged to coincide with the axis of rotation of the rotor 8, or if the shear stress modulator is designed in the form of a right-sided polyhedral prism, the prism is parallel to the edge of the prism. The axis passing through the beam is arranged to coincide with the axis of rotation of the rotor 8, or the shear stress modulator is designed in the form of a rotor with longitudinal and / or inclined recesses arranged on its side. The rotor is arranged such that its axis of rotation coincides with the axis of rotation of the rotor 8, wherein the first member 16 of the shear stress modulator is in relation to the surface of the second member 17 of the shear stress modulator. The second member 17 is rotatably mounted in a state of forming a ring-shaped slot 9, and the second member 17 has a low-profile ring-shaped ridge shape in which longitudinal and / or inclined recesses are arranged on the surface thereof. This ring-shaped ridge is mounted in the form of a ring-shaped slot 9 with respect to the surface of the first member 16 of the shear stress modulator, the narrow section of the ring-shaped slot 9 The width is equivalent to 10 to 90% of the width of the annular gap 10, characterized in that the device is further provided with compression screw cooling means 12 and / or casing cooling means in the compression zone 4. Polymer material processing apparatus.
    [14" claim-type="Currently amended] The method of claim 13, wherein the second member 17 of the shear stress modulator is disposed on the surface of the first member 16 of the shear stress modulator, or a portion thereof is on the surface of the first member 16 of the shear stress modulator and And the other part is disposed on the surface of the rotor (8).
    [15" claim-type="Currently amended] 14. Apparatus according to claim 13, characterized in that the ratio of the sum of the half heights of the members (16, 17) of the shear stress modulator to the diameter of the compression screw (5) is 0.01 to 0.5 to 1.
    [16" claim-type="Currently amended] 14. The apparatus of claim 13, wherein the rotating body of the first member (16) of the shear stress modulator has a disk or truncated ellipsoid shape.
    [17" claim-type="Currently amended] 14. The apparatus of claim 13, wherein the longitudinal and / or inclined recesses are arranged on the side of an elliptical cylinder or a right-sided polyhedral prism.
    [18" claim-type="Currently amended] The length of the short axis of the cross section of the elliptical cylinder is equal to the diameter of the rotor 8, while the length of the long axis of the cross section is the diameter of the rotor 8 and the width of the annular gap 10. Polymer material processing apparatus, such as the sum of.
    [19" claim-type="Currently amended] 14. Apparatus according to claim 13, characterized in that the first and / or second member (16, 17) of the shear stress modulator is further provided with cooling means.
    [20" claim-type="Currently amended] 14. Apparatus according to claim 13, characterized in that the first member (16) of the shear stress modulator is installed to be rotatable separately or in cooperation with the rotor (8) and / or the compression screw (5). .
    [21" claim-type="Currently amended] 14. Apparatus according to claim 13, characterized in that the kneading pins and / or plates are arranged on the side of the rotor (8).
    [22" claim-type="Currently amended] 14. Apparatus according to claim 13, characterized in that the spiral groove which facilitates the transport of material to the outlet (13) is arranged on the side of the rotor (8).
    [23" claim-type="Currently amended] The apparatus of claim 13, wherein the ring-shaped ridge is designed to be rectangular or trapezoidal.
    [24" claim-type="Currently amended] 14. The casing cooling means in the compression zone 4 and the casing cooling means in the grinding zone 6 are designed to be operable in cooperation with the casing cooling means 11 in the compression zone and the grinding zone. A polymer material processing apparatus.
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    同族专利:
    公开号 | 公开日
    WO2002016100A1|2002-02-28|
    JP2004513803A|2004-05-13|
    RU2173635C1|2001-09-20|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    2000-08-23|Priority to RU2000122140A
    2000-08-23|Priority to RU2000122140
    2001-08-22|Application filed by 바딤 젠나디에비치 니콜스키
    2001-08-22|Priority to PCT/RU2001/000343
    2003-05-27|Publication of KR20030041976A
    优先权:
    申请号 | 申请日 | 专利标题
    RU2000122140A|RU2173635C1|2000-08-23|2000-08-23|Method and device for processing of polymeric material |
    RU2000122140|2000-08-23|
    PCT/RU2001/000343|WO2002016100A1|2000-08-23|2001-08-22|Method for processing polymeric material and device for carrying out said method|
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